News

Production of raw materials for batteries from European resources

After Wednesday’s sessions on the EU political agenda, which outlined strategic measures to meet industry needs, attention shifted to the annual workshop of the Materials for batteries hub. Now in its 4th edition, the event was co-organised by Horizon Europe projects RELiEFFREE4LIBRESPECT and LITHOS. The focus of the workshop, true to its eponymous theme, was tackling one of Europe’s most urgent challenges: securing sustainable raw materials for batteries.

Under the inauguration of Oliver Schenk, Member of the European Parliament, this edition unfolded under the auspices of urgency, regulatory clarity and cross-border collaboration. The MEP called for swift implementation of the Critical Raw Materials Act and the Net Zero Industry Act, stressing the need for rapid permitting and the mobilisation of both public and private investment. “We cannot afford delays,” he warned. “This is about sovereignty.” His remarks were followed by strong appeals for cooperation among mining regions, manufacturing clusters, research centres and recycling hubs to build a resilient European value chain. He urged participants to contribute to upcoming legislative files, including the European Chips Act 2, the Circular Economy Act and the new EU budget, ensuring that the priorities of the battery materials community are embedded in future policies.

Nader Akil, founder of the Cluster Hub and moderator of the first technical session, emphasised on enhancing the dialogue between academia, industry and policy makers in order to ensure that these goals would be reached.

Following up with a presentation of his  most recent scientific publication – “Lindy Effect in Hydrometallurgy” [co-authored with Dr. Ir. Peter Tom Jones]  – Professor Koen Binnemans provided a frank look at the shortcomings in industrialising battery material innovations. Transferring hydrometallurgical advancements from lab to plant is slow, constrained by economics, regulation and what the authors call “the Lindy effect” – the tendency for established technologies to stand the test of time. Industry tends to favour incremental improvements to existing processes, such as reducing reagent consumption or increasing automation, rather than adopting entirely new chemistries, due to the high risks and costs associated with large-scale change. Launching a debating topic, audience questions shifted to technical and permitting challenges, concluding with the need for incremental innovation and pragmatic timelines.
Download the presentation

Various EU-funded R&I initiatives, members of the Cluster Hub, presented results and findings with the promise to reduce dependency on imports. LiCORNE project presented its intermediary results within the technical session “Mining and recovery”, alongside sister projects XRACT, CRM-Geothermal, METALLICO, ENICON LITHOS and RAWMINA.

Debating industrial integration, collaboration and European competitiveness

Two panels framed the bigger picture. The first one, chaired by Nader Akil (PNO Innovation Belgium), addressed scaling up technologies and reducing mining’s environmental footprint, with strong emphasis on AI and data-driven processes.

Read the entire review article

Producing battery-grade lithium compounds is one of the final steps in the LiCORNE value chain. Partners across Europe have been refining electrochemical and crystallisation processes to recover lithium as high-purity carbonate or hydroxide from diverse sources: brines, ores and recycled cathode materials.

Electrodialysis for lithium hydroxide production

Using the solutions derived from VITO’s upstream processes, SINTEF researchers have constructed and commissioned electrochemical cells for electrodialysis to convert lithium chloride (LiCl)  and sulfate (Li2SO4) solutions into lithium hydroxide (LiOH). Tests achieved:

Membrane flow cell setup © SINTEF

Organic-based membrane electrolysis

TECNALIA, advancing the organic-based membrane electrolysis, scaled up to a 10 cm2 electrolysis cell to test three types of solutions –those produced by the liquid-liquid extraction processes from brines and from spodumene leachates, and the off-specification cathode leachates. Outcomes include:

Off-specification cathode material A four-chamber setup recovered lithium and oxalic acid with yields above 95%, while the carbonation process produced Li2CO3 of >99% purity.
Brines and spodumene Li recovery is performed directly on the stripping dissolution obtained in the separation and purification steps, bypassing membrane-electrolysis. Carbonation delivered 88% purity for brines and 99% for spodumene.
PIMs [Polymer inclusion membranes] Tests confirmed lithium migration is possible, but further research is needed to improve conductivity and ensure efficient transport.

4-chamber flow cell diagram designed by TEC for lab experiments, © TECNALIA

Lithium purification and recovery via electrodialysis and electrolysis

The research group at Fraunhofer Institute for Chemical Technology ICT explored a simple, highly scalable method for Li2CO3 recovery using a combination of several methods like ion exchange (IE), reversed osmosis (RO), electrodialysis with bipolar membranes (EDBM), and Li2CO3-precipitation (see figure below). The goal was to recover high-purity lithium carbonate from Lithium-concentrated solutions provided by partners EnBW and KIT.

Setup for Li2CO3 recovery from Li-concentrated solutions starting with ion exchange, via reversed osmosis and electrodialysis | © Fraunhofer ICT

While ion exchange removed key impurities, the removal of Mn2+ ions (particular in EnBW samples) is still under investigation. Low contamination levels are crucial for electrodialysis and lifetime of EDBM. For KIT-sourced solutions, the process delivered Li₂CO₃ at 99.89% purity.

Selective chlorination and electrolysis of spodumene concentrate and waste cathode material

SINTEF researchers achieved selective chlorination of lithium from calcined spodumene concentrate and off-specification cathode waste, with yields exceeding 95%. Their selective chlorination converts insoluble oxides to soluble chlorides by electrolysis, thus extracting target elements: Li, Ni and Co. Experiments show:

Chlorination setup at SINTEF, © SINTEF

Gas-diffusion electrocrystallisation

The Gas-Diffusion Electrocrystallisation (GDEx), VITO’s proprietary technology, achieved >95% lithium extraction from geothermal and continental brines, spodumene effluents and cathode leachates. Downstream synthesis produced Li₂CO₃ with:

Schematic representation of the Gas-diffusion electrocrystallisation (GDEx) process, © VITO

[© Featured visual: Amadeus Bramsiepe]

With the corresponding work package already concluded, results on extraction of lithium and other critical metals from concentrates, ores, tailings and off-specification cathode materials are now available. The main goal of this work package has been to develop processes that are energy-efficient, environmentally safer, and equally suitable for industrial scale-up. 

Alkaline leaching of lithium 

Alkaline leaching promises a more economical alternative for processing spodumene concentrate and related minerals, by reducing operating temperatures and eliminating the need for aggressive chemicals. Researchers at NTUA developed and optimised the alkaline leaching of lithium from spodumene concentrate supplied by ECM and lithic mica from the mines operated by Imerys. The challenge they received was to achieve Li extraction rates exceeding 92% while maintaining low impurities levels in the Li-bearing aqueous solutions.  

The innovative alkaline leaching process developed by NTUA, © NTUA

A series of experiments were conducted on the α-spodumene concentrate and lithic mica, analysing key parameters such as the leaching solution concentration, the nature of additives, retention time and their effect on lithium leaching. Lithium extraction up to 100% was successfully achieved from lithic mica and 75% by spodumene concentrate.

Solvometallurgical extraction 

TEC’s advanced solvometallurgy approach uses deep eutectic solvents [DES] to extract lithium from spodumene concentrate, lithic mica and lithium phosphate, as well as lithium, cobalt and nickel from off-specification cathode material. This low-temperature process combines selectivity with solvent reusability, reducing environmental impact. Key outcomes show that Li, Co, Ni recovery exceeded 95% at room temperature. Moreover, organic solvents were reused up to ten times without loss of efficiency. 

Pre-treatment steps (ball milling and calcination) improved leaching performance, enhancing the recovery yields: 

Photo showing the Reactor used for the solvometallurgical leaching experiments

Reactor used for the solvometallurgical leaching experiments © TEC

Reactive milling

KIT researchers studied in depth various ball-milling parameters for the mechanochemical transformation of the off-specification cathode material samples provided by Umicore. After milling, water leaching separated lithium compounds from an insoluble metallic composite rich in nickel, manganese, and cobalt. Using aluminium as a reducing agent during ball milling, followed by aqueous leaching, the process achieved: 

By lowering temperatures, eliminating acid roasting, and enabling solvent reuse, these processes significantly reduce energy demand and chemical consumption. 

Reactive ball-milling of off-specification cathode material in presence of a reducing agent © KIT

The Horizon Europe project LiCORNE has completed an important milestone in its journey to establish a sustainable lithium supply chain in Europe. At the end of 30 months of research and technical development, the project consortium has selected three process flowsheets for upscaling. These routes represent the most promising routes for lithium recovery from European resources: ores, brines and off-specification battery cathode materials (waste). 

Why this matters? Europe, from its position as an ambassador of the green transition, is expected to see a major increase in demand for lithium. Yet, its contribution to the lithium supply chain remains modest, despite holding an estimated 5 % of the global reserves. Most of this lithium is locked in hard-rock deposits, which are generally costly and environmentally challenging to extract. Domestic mining projects often face public resistance, while refining capacity remains limited. 

Moreover, JRC’s studies indicate that despite a projected increase in EU’s battery cell production, the bloc remains import-reliant for battery-grade materialsRefined lithium inputs are expected to come increasingly from new EU mines, provided critical bottlenecks, such as domestic conversion and refining are removed. The Commission’s JRC additionally estimated that by 2040 recycled cobalt and nickel could meet up to 51 % and 42 % of EU demand, respectively. 

LiCORNE, short for Lithium recovery and battery-grade materials production from European resources, is one of the numerous R&I initiatives launched to address this strategic vulnerability. The project aims to build Europe’s first integrated lithium supply chain. Its mission spans beyond simply optimising technological processes to recover lithium and battery-grade materials, aiming to provide solutions that are both efficient, scalable and sustainable.  

Assessments and selection of flowsheets  

After three years of research and technology optimisation, the LiCORNE consortium has selected the flowsheets that will be further upscaled during the project’s last 12 months. This selection followed a two-step assessment: 

  1. Individual technology evaluation: 14 technologies developed and optimised within the technical work packages were assessed for environmental impact (via Life Cycle Assessment – LCA), economic performance (via Life Cycle Costing – LCC) This comprehensive assessment revealed additional insights that served as guiding lines in further optimisation at lab scale. 
  2. Flowsheet integration and ranking: the most promising technologies evaluated in the first assessment were combined. Each flowsheet was later evaluated using a ranking value that integrated LCA, LCC and product quality metrics. The functional unit applied to all process routes referred to 1 kg of lithium recovered in the final product, thus ensuring consistency and fair evaluation across different lithium compounds. 

The final ranking identified the following three flowsheets as candidates for upscaling: 

1. Spodumene route: 

2. Continental brine route: 

3. Off-specification cathode: 

A feasibility study was performed for the three candidate flowsheets before moving into scale-up phase. The study confirmed their readiness for implementation in line with equipment requirements, scalability and the project’s remaining budget envelope.

Various research partners involved in the LiCORNE project have been exploring different Li extraction technologies from Li-rich ores, tailings and off-specification cathode materials from battery production.  All these exploratory routes, including alkaline leaching [NTUA], advanced solvometallurgy [TEC] and reactive ball-milling [KIT], share common objectives, aiming to be more energy efficient and reduce the environmental impact.

TEC’s advanced solvometallurgy approach leverages deep eutectic solvents to extract lithium, providing an energy-efficient solution for selective removal. This technique is not only applicable to Li but also extends to the extraction of other critical elements contained in the off-spec cathode materials.

Meanwhile, KIT’s reactive ball-milling method is being explored as an effective battery recycling process. This innovative approach uses aluminium as a reducing agent for transition metals, which is already present in the input waste stream as the current collector material for electrodes. The process offers a direct route to battery-grade lithium carbonate.

Solvometallurgical extraction

TEC investigated and developed a solvometallurgical extraction process for lithium from spodumene concentrate, lithic mica and lithium phosphate, and for lithium, cobalt and nickel from off-specification cathode material. The optimised operating conditions and necessary pre-treatment steps enabled over  95% extraction of Li, Co and Ni from these materials at room temperature. Additionally, the reuse of the organic solvents utilised during the leaching processes was effectively tested proving that it does not affect the yield in the next cycles. The lithium containing liquid streams obtained are processed by TEC in further steps with different technologies towards the obtention of pure battery-grade lithium carbonate.

Reactor used for the solvometallurgical leaching experiments by TEC

Mechanochemical transformation

Researchers at KIT studied in depth various ball-milling parameters for the mechanochemical transformation of the off-specification cathode material samples provided by Umicore. Subsequent water leaching facilitated the separation of an insoluble metallic composite containing Ni, Mn and Co from water soluble Li-compounds. KIT researchers optimised various reducing agents – such as Al, Ca and Mg, achieving Li recovery exceeding 80 %, with a Li2CO3 purity of around 90 %.

Graph explaining the difference between different separation and purification processes for lithium

Product streams obtained by the various extraction technologies here explored will be further processed in subsequent separation and purification processes and lithium recovery methods. © KIT

Product streams obtained by the various extraction technologies here explored will be further processed in subsequent separation and purification processes and lithium recovery methods.

Opto-Magnetically Sorting System

During conventional mineral processing, significant resources are often lost during the beneficiation phase. Lithium-bearing particles trapped in the gangue can proceed to downstream stages, reducing the efficiency of the entire extraction process. To address this, researchers at TU Delft have developed an Opto-Magnetic Sorting System that significantly enhances the separation of lithium ores. This innovative technology combines precision liquid deposition and magnetic separation techniques, offering an advanced alternative to traditional gravity-based separation methods used in beneficiation circuits.

The process starts with lithium-bearing ores being crushed and sieved, isolating particles in the 2–4 mm size range for the next step – optical sorting. A high-resolution line scan camera captures continuous images of particles on a conveyor belt. These images are processed in real-time using a custom algorithm developed at TU Delft, which is trained to identify lithium-rich particles based on subtle colour differences.

Once identified, the target particles are selectively marked using magnetic powder. This enables the marked lithium-rich particles to be separated efficiently by a downstream magnetic conveyor into a dedicated container.

This innovative beneficiation approach has successfully prevented around 45% of the gangue material from entering the downstream process—nearly three times more efficient than the initially targeted improvement of 15%.

Ball milling-assisted chemical transformation of spodumene concentrate

According to the State-of-the-Art [SoA], processing spodumene takes place at high-temperatures [1100oC], with direct implications on the economic viability of the entire process. Researchers at TEC have been investigating an alternative to conventional processes. Their investigation features ball milling and calcination at lower temperatures than the conventional process, using additives when needed for the improvement of the next leaching step.

Ball milling is a mechanical process that induces self-sustaining reactions in many sufficiently exothermic powder mixtures. These exothermic reactions, which release a significant amount of heat, can influence both the microscopic and macroscopic properties of the resulting material. On a microscopic level, the heat generated by the reactions can cause changes in the crystal structure and composition of the material. On a macroscopic level, these changes can affect the material’s overall properties, such as its strength, hardness and reactivity. TECNALIA’s findings show that the combination of the ball milling with additives lower calcination temperatures required [200oC below the SoA] in the pre-treatment process of the samples and, also, allow milder conditions in the next processing phases (leaching).

The process, replicated on lithic mica and lithium phosphate materials, were also successful to achieve good results in the next leaching step.

The furnace used in the calcination pre-treatment by TECNALIA

In other research facilities, in different corners of Europe, other LiCORNE partners are reporting progress in producing battery-grade materials from various sources – brines, ores (spodumene for example) and off-specification cathode material.

Electrodyalysis for lithium hydroxide and carbonate production

Using the solutions derived from VITO-CAST team’s upstream processes, SINTEF researchers have constructed and commissioned electrochemical cells for electrodialysis of lithium chloride (LiCl) and lithium sulphate (Li2SO4) solutions. Researchers identified the optimal parameters to produce lithium hydroxide (LiOH) or lithium carbonate (Li2CO3), which achieved a current efficiency of approx. 40 % and a specific energy consumption of 20 kWh/kg. Further optimisation of the cell design is expected to reduce the energy consumption.

Membrane flow cell setup at SINTEF

Additionally, this process also produced a mix of Li2CO3 and LiOH through evaporative crystallisation, with a purity of almost 90 %, but showing sodium (Na) as the main impurity interfering with the process.

Organic-based membrane electrolysis

The organic-based membrane electrolysis, developed at TEC and tested on three types of solutions – those produced by the liquid-liquid extraction processes from brines and from spodumene leachates, and the off-specification cathode leachates – achieved up to 95 % Li yield, far beyond the levels established at the beginning of the project. Their tested carbonation method yielded a Li2CO3 with a purity exceeding 99% in the case of off-specification cathode material and spodumene concentrate materials. Not only the Li recovery target has been achieved, but also the solvent used in the former leaching process has been recovered and reused keeping the performance as initially, aiming for a more sustainable and circular process.

3-chamber Flow cell setup at TECNALIA

Lithium purification via electrodialysis and electrolysis

The research group at Fraunhofer Institute for Chemical Technology ICT explored a simple, highly scalable method for lithium purification using a combination of Ion Exchange (IE), Reversed Osmosis (RO) and Electrodialysis with bipolar membranes (EDBM) (see figure below). The goal was to recover high-purity lithium carbonate from Lithium-concentrated solutions provided by partners EnBW and KIT. The IE process effectively removed specific impurities (e.g. divalent cations). The significant level of impurities present in the solutions, provided by EnBW, prevented the electrodialysis with bipolar membranes. The EDBM process, applied uniquely on the samples sent by KIT, yielded a 99.89 % purity. However, the yield of the first precipitation step was determined to be around 35 %, highlighting the need for further optimisation in future precipitation cycles.

Setup to prepare Li2CO3 recovery from Li-concentrated solutions starting with ion exchange, via reversed osmosis and electrodialysis. © FRAUNHOFER

Selective chlorination and electrolysis of spodumene concentrate and waste cathode material

SINTEF researchers investigated the extraction of lithium and other valuable elements, such as Co, Ni, Mn from solid raw materials. They achieved selective chlorination of lithium from calcined spodumene concentrate and off-specification cathode waste in LiCl-KCl and CaCl2-NaCl-KCl melts. Theoretical assessments suggest that lithium can be subsequently electrowon from the LiCl-KCl mixture with a purity of approximately 99 %.

Chlorination apparatus at SINTEF

Gas-diffusion electrocrystallisation

VITO-ELEC team focused on internally-developed Gas-Diffusion Electrocrystallisation (GDEx) technology, which demonstrated high efficiency – achieving lithium extraction rates more than 95 %. VITO-ELEC team successfully extracted lithium from various sources, including geothermal brines, effluents from sorption processing of hard rock beneficiation and the leachates of off-specification cathode materials.

The team has produced lithium carbonate from the extracted lithium by implementing a downstream synthesis procecure. The process achieved a  >1 % lithium concentrate increase from geothermal brines and solid product eluates with over 20 % lithium concentration. Moreover, the energy consumption of the GDEx process was below 10 kWh per kg of Li2CO3, with over 90 % lithium recovery from all tested complex matrices.

On 12 December 2024, the third edition of the annual workshop of the Cluster Hub “Production of Raw Materials for Batteries from European Resources” took place in Brussels, being co-organised by EU-funded projects RHINOCEROS, CRM-geothermal and CICERO. This third edition, along with an increasing number membership, confirm the hub’s role as a dynamic ecosystem that continues to generate innovations in the European battery materials sector.

The hub’s annual workshop, held as a satellite event of the Raw Materials Week 2024, provided once again a platform for presenting the most promising results from participating projects. Two technical sessions covered the entire battery value chain, from raw materials mining to recycling, while the opening conveniently portrayed the policy, the regulatory and strategic frameworks that support and drive the EU R&I initiatives in the battery sector.

Policy perspectives and supporting mechanisms for the battery sector

Susana Xara, Project adviser on raw materials at European Health and Digital Executive Agency (HaDEA), established the discussions tone, navigating through the insights of the Critical Raw Materials Act [CRMA] and the Net Zero Industry Act [NZIA] and focusing on their contribution to securing a sustainable supply of critical raw materials for the European battery industry.

Download the opening keynote

Wouter IJzermans, BEPA Executive Director, presented the long-term vision and potential revisions of their roadmap, emphasising the importance of policy frameworks and incentives in promoting battery innovation and deployment across Europe.

Download BEPA presentation

The presentation of Vasileios Rizos from the Centre for European Policy Studies (CEPS) identified various barriers and challenges emerging from the EU policy framework on batteries, based on inputs from 20 companies across the entire battery value chain, including partners from the BATRAW project, member of the Cluster Hub since 2022. The representative of CEPS concluded with a set of policy messages referring to early dialogue channels established between policy-makers and various stakeholders. Before the legal requirements entry into force, this information exchange on availability of secondary data sets could enable stakeholders to assess the data quality, select suitable sets of information and identify potential data gaps.

Publicly available resources submitted by CEPS:

Download CEPS presentation

Orchestrating the launch and on-going work of the Cluster Hub, PNO Innovation Belgium [part of PNO Group – leader in innovation and funding consultancy], represented by Dr. Nader Akil, concluded the first session with an overview of all EU funding programmes supporting research, innovation and investment in raw materials production for batteries. Additional to the upcoming funding opportunities and guidance on selecting the appropriate funding opportunities based on the status of technology, Dr. Nader Akil introduced another initiative launched by PNO Group – DIAMONDS4IF. This project supports the preparation of Innovation Fund applications, enabling the transfer of H2020 research results into successful ventures and securing investment funding.

Download Funding Schemes presentation

Sustainable sourcing practices for battery materials from primary sources

The session of technical presentations debuted with RAWMINA project, represented by Carmen Estepa, R&D Manager at AGQ Mining & Bioenergy, providing an overview of its final results on the demonstration activities of an integrated innovative pilot system for CRMs recovery from mine wastes. Up-to-date results indicate encouraging extraction rates of ~90 % Fe, ~95 % Co and ~60 % antimony (Sb) yielded by the bioleaching process. Additionally, the alkaline leaching applied after bioleaching extracted more than 90 % tungsten (W), while the following processing step – Fe precipitation, confirmed that Fe and Sb can be removed almost completely from the solution (>90 %). Finally, the processes engaged in the selective CRM recovery yielded promising recovery rates in the range of 99 % for Co, 65 % for W, 77 % for Sb.

Download RAWMINA presentation

LiCORNE project presenting the feasibility of lithium extraction from geothermal brines

Dr. Albert Genter, Deputy General Manager of ES Géothermie, presented the geochemical characterisation of geothermal reservoir rocks in the Upper Rhine Graben – results of their activities conducted within the LiCORNE EU-funded project. After a short incursion into the geological formation of the Upper Rhine Graben (URG) area, Dr. Albert Genter highlighted the feasibility of lithium (Li) extraction from the geothermal brines. The high Li concentrations in the geothermal brine at Soultz-sous-Forêts and Rittershoffen [in the range of 150-200 mg/L], combined with significant water flows exploited by the geothermal power plants, indicate a great potential for Li production in the URG. After establishing the fluid circulation within the fractures of the geological formation, the research team at ES-G will continue investigating the chemical composition of sedimentary rocks, which are also part of the reservoir Soultz-sous-Forêts, and conducting Li and strontium (Sr) isotope analyses to provide more detailed information about the origin of lithium in the brine.

Download LiCORNE presentation

Dr. Nivea Magalhães [Univ. of Exeter, UK] presented the conclusions of the forensic geometallurgy protocol established within the ENICON project. Often, information not directly related to processing leads to limited insights into ore processing behaviour. ENICON investigates the impact of mineral textures and grain size on liberation, sometimes interfering with automated mineralogy results. Additionally, the project presented the findings of the ore characterisation of the Kevitsa mine, containing nickel (Ni)- and cobalt (Co)-bearing minerals.

The CRM-geothermal presentation, delivered by Saskia Bindschedler, Professor at Univ. de Neuchatel, Faculty of science, Institute of biology, Laboratory of microbiology, focused on the use of microbial activity for Li recovery from geothermal brines. Geothermal brines are characterised by high temperatures, increased pressure and salinity, conditions favourable for bioextraction processes using microbes. Key findings confirmed the feasibility of microbial-driven processes for Li recovery, enabling effective filtering of elements using oxalate compounds, followed by precipitation via oxalothropic bacteria, such as Pandoraea sp.. While the researchers will continue working on oxalotrophy and initial pH optimisation, focusing on improving the scalability, they will additionally investigate Li concentration in fluid samples.

Download CRM-geothermal presentation

An insight into the results of the METALLICO project, with focus on their COOL+ technology, was delivered by Sandra Pavon from Fraunhofer IKTS. COOL+ is one of the five technologies investigated within the framework of METALLICO, that involves a leaching step using supercritical CO2, that enables the extraction of Li in a more efficient and environmentally friendly manner. After explaining the five phases of the process and comparing the results at the main conclusions reported high selectivity and efficiency in Li recovery, achieving Li2CO3 which meets battery-grade specifications with a purity of 99.7 %. The solid silicate residue that remains after the CO2 leaching step is not wasted. Instead, it is repurposed to produce geopolymers which are further used in the construction sector, aligning with the principles of circular economy and zero-waste.

Download METALLICO presentation

On 16 October 2024, the Karlsruhe Institute of Technology (KIT) was hosting not only the LiCORNE project’s M24 consortium meeting, but also its first exploitation workshop. The event brought together a diverse group of stakeholders, with nearly 15 industry guests and members of the External Advisory Board (EAB), to discuss the latest advancements in lithium (Li) extraction technologies.

The workshop began with a welcome address by Dr. Lourdes Yurramendi [the coordinator of the LiCORNE initiative and Project Director at TECNALIA Waste Valorisation, Energy, Climate and Urban Transition], followed by Nader Akil, Operations Manager at PNO Innovation Belgium, who outlines the objectives of the exploitation workshop and provided an overview of the LiCORNE project. Funded by the European Commission, the project aims to develop competitive technologies for Li extraction and recovery from various feedstocks, including ores, geothermal brines and cathode waste materials. Following this introduction, various partners delivered technical presentations, showcasing their innovative approaches and key exploitable results after 24 months from the start of the project.

Regardless the feedstock considered, all these novel technologies share one theme: sustainability. This focus on sustainability translates into exploring research routes that go beyond the current state-of-the-art (SoA), reducing energy and water consumption and the generation of chemical waste:

Beyond technological presentations, the workshop also facilitated discussions with external participants, including members of the EAB and industry representatives. These exchanges provided valuable insights into the industry’s needs and opened up new routes for collaboration. To facilitate future collaborations, PNO presented several funding opportunities that can be used to bring the most promising technologies and the LiCORNE selected flowsheet to a pilot level.

As the project progresses, the focus will shift now towards the benchmarking and selection of the most promising LiCORNE technologies for upscaling to produce ~1 kg of battery-grade Li by the end of the project. This phase aims to shape a path towards larger piloting and future commercialisation.

Lithium’s role in the quest to facilitate the transition to zero-emission industry

With no surprise, after Europe’s quest to replace fossil fuels and turn towards clean energy, lithium (Li) has been classified as a key component, making it to the short list of EU’s highly significant critical raw materials. With the transition to zero-emission vehicles, carmakers, as the most consuming industrial sector, will need ever more Li for batteries.

Renowned for its policy background, the EU decisional institutions adopted the Critical Raw Materials Act (CRMA) in record time. This accelerated adoption procedure shows nothing but the need for action, which reflects Europe’s urge to secure a sustainable supply of critical raw materials (CRMs). The CRMA sets specific targets to strengthen the EU’s capacities along the different stages of the value chain, ensuring that by 2030:

Research and industry – hand-in-hand to demonstrate sustainable production of cathode materials for batteries from geothermal resources

Both EnBW and LevertonHELM are key partners in the LiCORNE project. EnBW, as one of the largest energy supply companies in Germany and Europe, has the following tasks in the LiCORNE project: 1) to supply geothermal brine feedstock, respectively to conduct develop Li+ desorption technology aiming at min. 90% yield from geothermal and continental brines. LevertonHELM, on the other side, is a Lithium chemicals producer based in the UK, focusing on the manufacturing of a wide range of inorganic Li chemicals. In the framework of LiCORNE, the British company will benchmark and qualify the Li produced by the processes developed in the project, as battery-grade material.

German, respectively British companies have expanded their collaboration beyond the project’s framework, with a joint objective to advance the sustainable production of battery-grade Li carbonate and Li hydroxide – essential materials for electric mobility and energy storage solutions.

In previous articles, EnBW reported high Li concentrations for the geothermal brines in the Upper Rhine Valley (Bruchsal reservoir), ranging from 163 to 190 mg/L (Sanjuan et al., 2016). However, due to the characteristics of the reservoir, featuring highly mineralised brines, the extraction process was hampered by an elevated additional concentration of foreign ions (TDS 130 g/l). According to Laura Herrmann, Project Manager Research and Development at EnBW, the process requires increased selective adsorption technology in line with the exigences of the battery materials producers.

EnBW and LevertonHELM produce Li carbonate for the first time from geothermal brine in Germany

This industrial collaboration has resulted in a remarkable purity of 99.5% for lithium carbonate, demonstrating great potential for further scale-up to meet the EU’s demand for lithium.

Using direct Li extraction by adsorption (A-DLE), the process coordinated by the industrial partnership led to a remarkable purity of 99.5 % for Li carbonate. This successful initial trial holds promise for future upscale, potentially meeting the EU’s demand for Li.

Curious to learn more about the Direct Lithium Extraction technologies developed and tested in LiCORNE?

Register to the Symposium on Direct Lithium Extraction

© visual:EnBW